Engineers create new type of matter

Engineers at the California Institute of Technology, working with colleagues from Lawrence Livermore National Laboratory and Princeton University, have developed a new type of matter, neither granular nor crystalline, that responds to some stresses as a fluid would and to others like a solid. The new material, known as PAM (for polycatenated architected materials) could have uses in areas ranging from helmets and other protective gear to biomedical devices and robotics.

PAMs’ basic form is similar to that of chain mail, with interlocking shapes linked together to form three-dimensional patterns whose configurations are almost unimaginably variable. The resulting materials, which Chiara Daraio, the G Bradford Jones professor of mechanical engineering and applied physics and heritage medical research institute investigator, and her colleagues have rendered using 3D printers, exhibit behaviours not found in other types of materials.

Wenjie Zhou, postdoctoral scholar research associate in mechanical and civil engineering, has been working on these types of materials for two years in Daraio’s lab. ‘I was a chemist, and I wanted to make these structures at a molecular scale, but that proved too challenging. In order to get answers to the questions I had about how these structures behave, I decided to join Chiara’s group and study PAMs at a larger scale.’

The PAMs that Daraio’s group created and studied were first modelled on a computer and were designed to replicate lattice structures found in crystalline substances but with the crystal’s fixed particles replaced by entangled rings or cages with multiple sides.

These lattices were then printed out three-dimensionally using a variety of materials, including acrylic polymers, nylon and metals. Once the PAMs could be held in the palm of one’s hand –most of the prototypes are five-centimetre cubes or spheres with a five-centimetre diameter –they were exposed to various types of physical stress. ‘We started with compression,’ Zhou explained, ‘compressing the objects a bit harder each time. Then we tried a simple shear, a lateral force, like what you would apply if you were trying to tear the material apart. Finally, we did rheology tests, seeing how the materials responded to twisting, first slowly and then more quickly and strongly.’

In some scenarios, the PAMs behaved like liquids. ‘Imagine applying a shear stress to water,’ Zhou said. ‘There would be zero resistance. Because PAMs have all these coordinated degrees of freedom, with the rings and cages they are composed of sliding against one another as the links of a chain would, many have very little shear resistance.’ But when these structures are compressed, they may become fully rigid, behaving like solids.

This dynamism makes PAMs unique. ‘PAMs are really a new type of matter,’ Daraio said. ‘We all have a clear distinction in mind when we think of solid materials and granular matter. Solid materials are often described as crystalline lattices. This is what you see in the classic ball-and-stick models of atomic, chemical, or larger crystalline structures. It is these materials that have formed our conventional understanding of solid matter. The other class of materials is granular, as we see in substances like rice, flour, or ground coffee. These materials are made up of discrete particles, free to move and slide relative to one another.’

PAMs defy this binary classification. ‘With PAMs, the individual particles are linked as they are in crystalline structures, and yet, because these particles are free to move relative to one another, they flow, they slide on top of each other, and they change their relative positions, more like grains of sand,’ Daraio explained. ‘PAMs can be very different from one another. You can print them in squishy materials or hard ones. You can change the shape of each particle, and you can change the lattice that you use to connect these particles. Each of these parameters affects the behaviour of the resulting material. But all of them show a characteristic transition between fluid- and solid-like behaviour. This transition may happen under different circumstances, but it always happens.’

‘Architected materials have been a significant subfield in material science and engineering for the past 20–30 years,’ Daraio said. ‘But as hybrids between granular materials and elastic deformable materials, PAMs are exciting and new. We have theories to describe granular matter and theories to describe elastic deformable matter, but nothing that captures these in-between materials. It’s a fascinating frontier that promises to redefine what materials are and how they behave.’

At this point, potential uses for PAMs are largely speculative but nevertheless intriguing, Daraio said: ‘These materials have unique energy-absorption properties. Because each element can slide and rotate and reorganise relative to each other, they can dissipate energy very efficiently,’ making them better candidates for use in helmets or other forms of protective gear than the currently used foams. This property makes them similarly attractive for use in packaging or in any environment where cushioning or stabilisation is required.

Experiments with microscale PAMs have shown that they will expand or contract in response to applied electrical charges as well as physical forces, suggesting possible uses in biomedical devices or soft robotics.

The research has been published in Science.